Tributylstannane → tetrahydro-2-[[1-[2-(tributylstannyl)-E-ethenyl]nonyl]oxy]-2H-pyran

Participants

Role	Name	HCID	Charge
Reactant	Tributylstannane	HCID 5948	—
Reactant	2-[(1-ethynylnonyl)oxy]tetrahydro-2H-pyran	HCID 12381804	—
Product	tetrahydro-2-[[1-[2-(tributylstannyl)-E-ethenyl]nonyl]oxy]-2H-pyran	HCID 14582853	—

Reaction Conditions

Temperature	110 °C

Reaction Steps

To 0.05g (0.19 mmol) of the titled product of Example 8 is addd 0.6ml (0.22mmol) of tri-n-butyltin hydride, and 20mg of azoisobutyronitrile (AIBN). The reaction mixture was heated at 110°C for 3 hours, whereupon thin layer chromatography indicated that the reaction was complete, producing the titled product. The product was used without further purification.

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US04855324
Source dataset	uspto-grants-1989_08
ORD ID	ord-7fabf3b20d944330b867a251da0f9db1
Source note	uspto-grants-1989_08