HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonium → Ammonium
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonium | HCID 223 | — |
| Reactant | Nitrate | HCID 943 | — |
| Reactant | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| Reactant | 2-Hydroxymuconic semialdehyde | HCID 5280366 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Ammonium | HCID 223 | — |
| Product | Picolinic acid | HCID 1018 | — |
Reaction Steps
A culture of strain CEL 2052 (ATCC 39636), growing continuously on 20 mM glucose and 8.5 mM nitrate, is induced with toluene in the absence of ammonium ions. 2-Hydroxymuconic semialdehyde is observed to accumulate rapidly at a rate which would produce 0.082 g/gdw/hr of picolinic acid if excess ammonium ions had been present. Instead, growth is inhibited immediately and the culture washes out at a dilution rate of 0.12 hr-1.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04859592 |
| Source dataset | uspto-grants-1989_08 |
| ORD ID | ord-d6c0bae2939e4be7af6e7dd9f529e1f5 |
| Source note | uspto-grants-1989_08 |