Sodium Cyanate → HCID 178454909, compound

HRID 1723271Notes

Reaction equation

HRID 1723271 reaction equation
[CH2:1]([CH2:4][PH:5](Cl)=[O:6])[CH:2]=[CH2:3].[O-:8][C:9]#[N:10].[Na+]>C(#N)C>[CH2:1]([CH2:4][PH:5]([N:10]=[C:9]=[O:8])=[O:6])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 517096Sodium CyanateHCID 178454907HCID 178454907, compound

Product 1

HCID 178454909HCID 178454909, compoundYield 71%

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

166 g (1.2 mol) of allylmethylphosphinic acid chloride were dissolved in 300 ml of acetonitrile and heated with 78 g (1.2 mol) of sodium cyanate to 50°-55° C. with stirring. After 5.5 hours, the precipitate was filtered off by suction and washed with acetonitrile; the filtrate was concentrated and the residue distilled at a temperature of 78°-80° C. and at a pressure of 25 Pa. 123 g of allylmethylphosphinic acid isocyanate (71% of theory) were obtained.

Workup

  1. filtrationthe precipitate was filtered off by suction
  2. washwashed with acetonitrile
  3. concentrationthe filtrate was concentrated
  4. distillationthe residue distilled at a temperature of 78°-80° C. and at a pressure of 25 Pa

Sources & evidence

ORD record
ord-a2ef5062653c48c5bcd83279cdc49cfe
Source dataset
uspto-grants-1989_08
Patent number
US04859795

Reaction notes

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