Sodium Cyanate → HCID 178523995, compound

HRID 1723273Notes

Reaction equation

HRID 1723273 reaction equation
[C:1]1([CH:7]=[CH:8][PH:9](Cl)=[O:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[O-:12][C:13]#[N:14].[Na+]>C(#N)C>[C:1]1([CH:7]=[CH:8][PH:9]([N:14]=[C:13]=[O:12])=[O:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 517096Sodium CyanateHCID 178527036HCID 178527036, compound

Product 1

HCID 178523995HCID 178523995, compoundYield 77%

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

106 g (0.57 mol) of phenylvinylphosphinic acid chloride were dissolved in 150 ml of acetonitrile and stirred with 38 g (0.59 mol) of sodium cyanate at a temperature of 30° C. After 23 hours, the precipitate was filtered off by suction and washed with acetonitrile; the filtrate was concentrated and the residue distilled at a temperature of 107°-110° C. and at a pressure of 33 Pa. 84 g of phenylvinylphosphinic acid isocyanate (77% of theory) were obtained.

Workup

  1. filtrationthe precipitate was filtered off by suction
  2. washwashed with acetonitrile
  3. concentrationthe filtrate was concentrated
  4. distillationthe residue distilled at a temperature of 107°-110° C. and at a pressure of 33 Pa

Sources & evidence

ORD record
ord-80df9f7e080549d29f22a39c7feea2ac
Source dataset
uspto-grants-1989_08
Patent number
US04859795

Reaction notes

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