HCID 10105603, compound → 5-(5-Acetyl-2-furanyl)pentanol

HRID 1723347Notes

Reaction equation

HRID 1723347 reaction equation
C([O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]1[O:11][C:12]([C:15](=[O:17])[CH3:16])=[CH:13][CH:14]=1)(=O)C.C[O-].[Na+]>CO>[C:15]([C:12]1[O:11][C:10]([CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][OH:4])=[CH:14][CH:13]=1)(=[O:17])[CH3:16]

Participants

4

Reactant 2

HCID 10105603HCID 10105603, compoundHCID 10942334Sodium Methoxide

Product 1

HCID 103303035-(5-Acetyl-2-furanyl)pentanolYield 74.7%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

5-(5-Acetyl-2-furanyl)pentanol acetate (60.6 g) was hydrolyzed with 3 g of sodium methoxide in 900 ml of absolute methanol and the product isolated to give 37.3 g of 5-(5-acetyl-2-furanyl)pentanol, b.p. 132°-135° C. (0.1 mm).

Workup

  1. customthe product isolated

Sources & evidence

ORD record
ord-d465b416f3704c29bb12436c3887e572
Source dataset
uspto-grants-1989_08
Patent number
US04861791

Reaction notes

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