HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → Methyl 13-chloro-13-oxotridecanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 13-Methoxy-13-oxotridecanoate | HCID 22939815 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | Methyl 13-chloro-13-oxotridecanoate | HCID 12956021 | — |
Reaction Steps
To a cold solution of 4.8 gms monomethyl 1,11-undecanedicarboxylate in 10 ml CH2Cl2 was added 5 ml SOCl2 dropwise over 5 minutes; then it was stirred at room temperature for 18 hours. The solvent was removed in vacuo to give 4.8 gms of an oily residue which was used without further purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04861798 |
| Source dataset | uspto-grants-1989_08 |
| ORD ID | ord-a3b8a410019249238590f91b3d9c5280 |
| Source note | uspto-grants-1989_08 |