Dibutylamine → HCID 10136947, compound

HRID 1723510Notes

Reaction equation

[CH2:1]([NH:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].Cl[CH2:11][CH2:12][CH2:13][O:14][C:15]1[CH:20]=[CH:19][C:18](/[CH:21]=[CH:22]/[C:23]2[O:24][C:25]3[CH:31]=[CH:30][C:29]([CH3:32])=[CH:28][C:26]=3[N:27]=2)=[CH:17][CH:16]=1>>[CH2:1]([N:5]([CH2:11][CH2:12][CH2:13][O:14][C:15]1[CH:16]=[CH:17][C:18](/[CH:21]=[CH:22]/[C:23]2[O:24][C:25]3[CH:31]=[CH:30][C:29]([CH3:32])=[CH:28][C:26]=3[N:27]=2)=[CH:19][CH:20]=1)[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4]

Participants

Reactant 2

HCID 8148Dibutylamine

HCID 14146344HCID 14146344, compound

Product 1

HCID 10136947HCID 10136947, compoundYield 22%

Procedure

Reaction of this product (2.2 g, 6.8 mmol) with dibutylamine produced 0.65 g (22% yield) of the title compound as the HCl salt, mp 143°-144° C. IR(KBr): 1600 cm-1. MS: 421(MH+). 1H NMR (CDCl3): δ 7.21-6.87 (m, 10H), 4.16 (t, J=5.6 Hz, 2H), 3.11 (m, 6H), 2.51 (s, 3H), 2.51-0.88 (m, 16H).

Sources & evidence

ORD record: ord-5dba9ae6e1994317a4de84cf98a330a9
Source dataset: uspto-grants-1989_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04861897

Reaction notes

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