Dibutylamine → HCID 14146375, compound

HRID 1723521Notes

Reaction equation

[CH2:1]([NH:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].Cl[CH2:11][CH2:12][CH2:13][O:14][C:15]1[CH:20]=[CH:19][C:18](/[CH:21]=[CH:22]/[C:23]2[S:24][C:25]3[CH:31]=[C:30]([O:32][CH3:33])[CH:29]=[CH:28][C:26]=3[N:27]=2)=[CH:17][CH:16]=1>>[CH2:1]([N:5]([CH2:11][CH2:12][CH2:13][O:14][C:15]1[CH:16]=[CH:17][C:18](/[CH:21]=[CH:22]/[C:23]2[S:24][C:25]3[CH:31]=[C:30]([O:32][CH3:33])[CH:29]=[CH:28][C:26]=3[N:27]=2)=[CH:19][CH:20]=1)[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4]

Participants

Reactant 2

HCID 8148Dibutylamine

HCID 14146367HCID 14146367, compound

Product 1

HCID 14146375HCID 14146375, compoundYield 52%

Procedure

Reaction of this product (2.0 g, 5.6 mmol) with dibutylamine produced 1.3 g (52% yield) of the named compound as the HCl salt, mp 190°-200° C. IR(KBr); 1600 cm-1. MS: 453(MH+). 1H NMR (CDCl3): δ 7.41-6.88 (m, 9H), 4.13 (t, 2H), 3.91 (s, 3H), 3.09 (m, 6H), 2.41-0.88 (m, 16H).

Sources & evidence

ORD record: ord-05412ad5cf8e477d8897d188d14f11d2
Source dataset: uspto-grants-1989_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04861897

Reaction notes

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