Dibutylamine → HCID 14146386, compound

HRID 1723523Notes

Reaction equation

HRID 1723523 reaction equation
[CH2:1]([NH:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].Cl[CH2:11][CH2:12][O:13][C:14]1[CH:19]=[CH:18][C:17](/[CH:20]=[CH:21]/[C:22]2[S:23][C:24]3[CH:30]=[CH:29][CH:28]=[CH:27][C:25]=3[N:26]=2)=[CH:16][CH:15]=1>>[CH2:1]([N:5]([CH2:11][CH2:12][O:13][C:14]1[CH:15]=[CH:16][C:17](/[CH:20]=[CH:21]/[C:22]2[S:23][C:24]3[CH:30]=[CH:29][CH:28]=[CH:27][C:25]=3[N:26]=2)=[CH:18][CH:19]=1)[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4]

Participants

3

Reactant 2

HCID 8148DibutylamineHCID 14146369HCID 14146369, compound

Product 1

HCID 14146386HCID 14146386, compoundYield 36%

Procedure

Reaction of this product (2.0 g, 6.3 mmol) with dibutylamine produced 1.1 g (36% yield) of the named compound as the HCl salt, mp 172°-173° C. IR(KBr): 3400, 1600 cm-1. MS: 409(MH+). 1H NMR (CDCl3): δ 8.37-6.79 (m, 10H), 4.67 (t, J=5.4 Hz, 2H), 3.55 (t, J=5.4 Hz, 2H), 3.12 (m, 4H), 1.99-0.79 (m, 14H).

Sources & evidence

ORD record
ord-f6fe8ed7dc65419b918078dcf1317647
Source dataset
uspto-grants-1989_08
Patent number
US04861897

Reaction notes

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