Methyl iodide → HCID 57564985, compound

HRID 1726860Notes

Reaction equation

HRID 1726860 reaction equation
CI.[CH3:3][N:4]1[CH2:9][CH2:8][N:7]([C:10]2[CH:15]=[CH:14][N:13]=[C:12]([C:16]3[NH:17][C:18]([C:23]4[CH:28]=[C:27]([N:29]5[CH2:34][CH2:33][N:32]([CH3:35])[CH2:31][CH2:30]5)[CH:26]=[CH:25][N:24]=4)=[CH:19][C:20](=[O:22])[CH:21]=3)[CH:11]=2)[CH2:6][CH2:5]1>C(#N)C>[CH2:35]([N:32]1[CH2:31][CH2:30][N:29]([C:27]2[CH:26]=[CH:25][N:24]=[C:23]([C:18]3[NH:17][C:16]([C:12]4[CH:11]=[C:10]([N:7]5[CH2:6][CH2:5][N:4]([CH2:3][CH2:12][CH2:16][CH3:21])[CH2:9][CH2:8]5)[CH:15]=[CH:14][N:13]=4)=[CH:21][C:20](=[O:22])[CH:19]=3)[CH:28]=2)[CH2:34][CH2:33]1)[CH2:11][CH2:10][CH3:15]

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 57564982HCID 57564982, compound

Product 1

HCID 57564985HCID 57564985, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

0.124 ml (1.99 mmol) of methyliodide are added dropwise to a suspension of 568 mg (0.994 mmol) 4,4″-bis-(4-methy-piperazin-1-yl)-1′H-[2,2′;6′,2″]terpyridin-4′-on in 18 ml acetonitril. The solution is stirred for 16 h at room temperature. The obtained whitish product (C33H49I2N7O) is filtered off and washed (with acetonitrile).

Workup

  1. filtrationThe obtained whitish product (C33H49I2N7O) is filtered off
  2. washwashed (with acetonitrile)

Sources & evidence

ORD record
ord-a3ba594f1b4a41c0a60759408bbe99e4
Source dataset
uspto-grants-2009_02
Patent number
US07494964B2

Reaction notes

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