化工社化工社 化学情報印刷レポート · 研究参考用
(4-Benzyloxy-naphthalen-1-yloxy)-acetic Acid Ethyl Ester → (4-Hydroxy-naphthalen-1-yloxy)-acetic acid ethyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (4-Benzyloxy-naphthalen-1-yloxy)-acetic Acid Ethyl Ester | HCID 69035941 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | (4-Hydroxy-naphthalen-1-yloxy)-acetic acid ethyl ester | HCID 69037588 | 73.6% |
反応手順
2.23 g (6.62 mmol) of (4-benzyloxy-naphthalen-1-yloxy)-acetic acid ethyl ester was dissolved in 20 ml of tetrahydrofuran and hydrogenated over 0.5 g of 10% of palladium on charcoal as catalyst at ambient temperature and atmospheric pressure. Filtering off the catalyst and evaporating the solvent yielded 1.2 g of the title compound as light brown solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07495001B2 |
| 出典データセット | uspto-grants-2009_02 |
| ORD ID | ord-c012bd1cc1394387a1f392d36b6dc0eb |
| 出典メモ | uspto-grants-2009_02 |