HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → Methyl 4'-(bromomethyl)biphenyl-2-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | (1,1'-Biphenyl)-2-carboxylic acid, 4'-methyl-, methyl ester | HCID 1393873 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | Methyl 4'-(bromomethyl)biphenyl-2-carboxylate | HCID 11012181 | — |
Reaction Steps
2.0 g of methyl 2-(4-methylphenyl)benzoate, 1.6 g of N-bromosuccinimide and 0.05 g of α,α'-azobis(isobutyronitrile) were heated in 110 ml of carbon tetrachloride under reflux for 2 hr. The succinimide was filtered off. The filtrate was concentrated, and the residue was recrystallized from a mixed solvent of n-hexane-isopropyl ether to prepare 1.6 g of the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05328911 |
| Source dataset | uspto-grants-1994_07 |
| ORD ID | ord-4f44f78ea5d542e78a6233a6c31553cd |
| Source note | uspto-grants-1994_07 |