反应详情

温度

60 °C

A mixed rare earth nitrate aqueous solution was prepared by dissolving 94.5 g of yttrium oxide and 5.5 g of europium oxide in 200 ml of a concentrated nitric acid followed by the addition of water to make up a volume of 3.3 liters. Separately, an aqueous ammoniacal oxalic acid solution was prepared by dissolving 240 g of oxalic acid dihydrate in 6.6 liters of water and adding 290 ml of a 28% ammonia water thereto. The mixed rare earth nitrate solution cooled to room temperature was added gradually to this oxalic acid solution under agitation at room temperature taking 20 minutes and agitation was further continued for additional 10 minutes. The pH value of the aqueous medium was 2.0. The precipitate thus formed was collected by filtration under suction and repeatedly washed with deionized water until no nitrate ions could be detected in the washing taking 1.5 hours as measured from the start of the precipitation reaction. The precipitate after washing was added to 8 liters of deionized water at 50° C. and dispersed therein by agitation and the dispersion was agitated for 4 hours at 60° C. The dispersion was filtered to collect the precipitate which was dried and calcined for 2 hours at 900° C. to give a powder of mixed rare earth oxide of yttrium and europium. This oxide powder was examined by the scanning electron microscopy to find that the particles mostly has a polyhedral configuration. The powder had a specific surface area of 6.8 m2 /g as determined by using an instrument Flow Souve 2300 (manufactured by Micromeritex Co.), an average particle diameter of 1.71 μm as determined by using a Fischer Subsieve Sizer Model 95 (manufactured by Fischer Co.) and a QD value of 0.20 calculated from a cumulative particle volume distribution curve prepared by using the histogram of the volume fractions of particles obtained by using a Coulter Model TA-II (manufactured by Coulter Electronics Co.) and shown in FIG. 1 of the accompanying drawing.

1. waitagitation was further continued for additional 10 minutes
2. customThe precipitate thus formed
3. filtrationwas collected by filtration under suction
4. washrepeatedly washed with deionized water until no nitrate ions
5. waittaking 1.5 hours
6. customas measured from the start of the precipitation reaction
7. washThe precipitate after washing
8. additionwas added to 8 liters of deionized water at 50° C.
9. additiondispersed
10. filtrationThe dispersion was filtered
11. customto collect the precipitate which
12. customwas dried
13. waitcalcined for 2 hours at 900° C.