HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → 5-(Chloro)carbonyl-6-nitro-1,3-benzodioxole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 6-Nitro-1,3-benzodioxole-5-carboxylic acid | HCID 246435 | — |
| Product | 5-(Chloro)carbonyl-6-nitro-1,3-benzodioxole | HCID 15563894 | — |
Reaction Steps
5 g (0.23 mole) of 4,5-methylenedioxy-2-nitrobenzoic acid are suspended in 50 ml of thionyl chloride and refluxed for 2 hours. The solution obtained is concentrated under reduced pressure. The residual oil crystallizes immediately after the addition of 50 ml of petroleum ether. The crystals are spun and recrystallized in ether.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05332735 |
| Source dataset | uspto-grants-1994_07 |
| ORD ID | ord-060e3bda1d9443359733d5c7239da5fd |
| Source note | uspto-grants-1994_07 |