Carbon Tetrachloride → HCID 19013034, compound

HRID 1729488Notes

Reaction equation

HRID 1729488 reaction equation
[C:1]([Cl:5])(Cl)([Cl:3])[Cl:2].[Cl-].[Al+3].[Cl-].[Cl-].[Cl:10][C:11]1[CH:16]=[CH:15][C:14]([F:17])=[C:13]([Cl:18])[C:12]=1[Cl:19]>>[Cl:10][C:11]1[C:12]([Cl:19])=[C:13]([Cl:18])[C:14]([F:17])=[CH:15][C:16]=1[C:1]([Cl:5])([Cl:3])[Cl:2]

Participants

4

Reactant 3

HCID 5943Carbon TetrachlorideHCID 142094Benzene, 1,2,3-trichloro-4-fluoro-HCID 6451240Aluminum(III) Chloride

Product 1

HCID 19013034HCID 19013034, compoundYield 62.8%

Procedure

Into a 200 ml four-necked-flask equipped with a stirrer, a reflux condenser, a thermometer and a dropping funnel, 97 ml (1 mol) of carbon tetrachloride and 26.7 g (0.2 mol) of aluminum chloride were charged, and 20.0 g (0.1 mol) of 1,2,3-trichloro-4-fluorobenzene was dropwise added under reflux. Thereafter, the mixture was reacted for 30 minutes. The reaction mixture was treated in the same manner as in Example 1 to obtain 19.9 g (yield: 62.8%) of 2,3,4-trichloro-5-fluorobenzotrichloride.

Workup

  1. customInto a 200 ml four-necked-flask equipped with a stirrer, a reflux condenser
  2. temperatureunder reflux
  3. customThereafter, the mixture was reacted for 30 minutes
  4. additionThe reaction mixture was treated in the same manner as in Example 1

Sources & evidence

ORD record
ord-b35d32ea34474353ad01f1c4a6d0cca1
Source dataset
uspto-grants-1994_07
Patent number
US05332851

Reaction notes

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