Methyl acetoacetate → HCID 86746167, compound

HRID 1729514Notes

Reaction equation

HRID 1729514 reaction equation
[CH:1]1[C:14]2[C:13](=[CH:15]/[CH:16]=[CH:17]/[CH:18]=[O:19])[C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[S:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[C:20]([O:26][CH3:27])(=[O:25])[CH2:21][C:22]([CH3:24])=[O:23]>>[CH:11]1[C:12]2[C:13](=[CH:15]/[CH:16]=[CH:17]/[CH:18]([OH:19])[CH2:24][C:22](=[O:23])[CH2:21][C:20]([O:26][CH3:27])=[O:25])[C:14]3[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=3)[S:6][C:7]=2[CH:8]=[CH:9][CH:10]=1

Participants

3

Reactant 2

HCID 7757Methyl acetoacetateHCID 19013055HCID 19013055, compound

Product 1

HCID 86746167HCID 86746167, compound

Procedure

By the method of Example 1, (E)-4-(thioxanthen-9-ylidene)-2-butenal (1.94 g, 7.34 mmol) was reacted with methyl acetoacetate to form present title product, 1.43 g.

Sources & evidence

ORD record
ord-4a3cfa7ad57e4c558bbb8d829350bd06
Source dataset
uspto-grants-1994_07
Patent number
US05332857

Reaction notes

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