HCID 21501105, compound → HCID 21501132, compound

HRID 1729779Notes

Reaction equation

HRID 1729779 reaction equation
[OH:1][CH:2]([CH2:5][CH2:6][CH2:7][CH:8]([OH:19])[CH2:9][CH2:10][CH2:11][CH:12]([O:14][C:15]([CH3:18])([CH3:17])[CH3:16])[CH3:13])[CH:3]=[CH2:4]>C1C=CC=CC=1.[O-2].[O-2].[Mn+4]>[OH:19][CH:8]([CH2:9][CH2:10][CH2:11][CH:12]([O:14][C:15]([CH3:16])([CH3:18])[CH3:17])[CH3:13])[CH2:7][CH2:6][CH2:5][C:2](=[O:1])[CH:3]=[CH2:4]

Participants

4

Reactant 1

HCID 21501105HCID 21501105, compound

Product 1

HCID 21501132HCID 21501132, compound

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 241BenzeneSolvent

Procedure

Crude 3,7-dihydroxy-11-(t-butoxy)-dodec-1-ene (5.8 g., prepared as described above) was dissolved in benzene (200 ml.) and the reaction mixture was then stirred for 2 hours at 25° after addition of activated manganese dioxide (58 g.). Filtration and evaporation of the filtrate at 30° in vacuo afforded crude 7-hydroxy-11-(t-butoxy)-dodec-1-en-3-one.

Workup

  1. filtrationFiltration and evaporation of the filtrate at 30° in vacuo

Sources & evidence

ORD record
ord-8f751b122ada4a44842f862407136da4
Source dataset
uspto-grants-1976_11
Patent number
US03989724

Reaction notes

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