HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Butanethione → 5-Chloro-2-methylindole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Butanethione | HCID 9548692 | — |
| Reactant | N,4-Dichloroaniline | HCID 12279953 | — |
| Product | 5-Chloro-2-methylindole | HCID 70636 | 72% |
Reaction Steps
This compound was prepared from N-chloro-4-chloroaniline and methylthioacetone following Method A, which gave 6.68 g (0.032 mol, 72%) of the sub-titled product: mp. 64°-64.5° (recr. from cyclohexane ir (KBr) 3350 cm-1 (NH); pmr (CCl4), 2.42 (1H,s,NH), 2.52 and 3.15 (1 resp. 2H,m,aromatic H), 7.72 and 7.90 (3H, s, CH3 and SCH3).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03992392 |
| Source dataset | uspto-grants-1976_11 |
| ORD ID | ord-590b9cfc97354c71818ff9f1474837bc |
| Source note | uspto-grants-1976_11 |