HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromodecane → Decyl thiocyanate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromodecane | HCID 8173 | — |
| Reactant | Sodium thiocyanate | HCID 516871 | — |
| Reactant | Tricaprylylmethyl ammonium chloride | HCID 77620884 | — |
| Solvent | Water | HCID 962 | — |
| Product | Decyl thiocyanate | HCID 79301 | — |
Reaction Steps
A mixture of 100 grams (0.45 mole) of 1-bromodecane, 160 grams (1.98 moles)of sodium thiocyanate, 50 ml water and 10 grams of tricaprylylmethylammonium chloride was heated to 88°-105° C with stirring over a period of 2 hours. Examination of the reaction mixture by gas liquid partition chromatography showed that 100% conversionof the 1-bromodecane had occurred to give 1-thiocyanodecane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03992432 |
| Source dataset | uspto-grants-1976_11 |
| ORD ID | ord-40daf765ff7f42f69c9e152c4d0c32ab |
| Source note | uspto-grants-1976_11 |