Sodium Azide → HCID 21497540, compound

HRID 1730391Notes

Reaction equation

HRID 1730391 reaction equation
C1O[C:4]([CH:17](Br)[CH3:18])([CH2:5][N:6]2[C:10](=[O:11])[C:9]3=[CH:12][CH:13]=[CH:14][CH:15]=[C:8]3[C:7]2=[O:16])[O:3]C1.[N-:21]=[N+:22]=[N-:23].[Na+]>CS(C)=O>[C:10]1(=[O:11])[N:6]([CH2:5][C:4](=[O:3])[CH:17]([N:21]=[N+:22]=[N-:23])[CH3:18])[C:7](=[O:16])[C:8]2=[CH:15][CH:14]=[CH:13][CH:12]=[C:9]12

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 21497601HCID 21497601, compound

Product 1

HCID 21497540HCID 21497540, compound

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

In the manner given in example 3, 1-phthalimido-3-bromo-2-butanone ethyleneketal in dimethyl sulfoxide is heated with sodium azide to give 1-phthalimido-3-azido-2-butanone, ethylene ketal.

Sources & evidence

ORD record
ord-061585ec796348c191cb899bc5abfc6f
Source dataset
uspto-grants-1976_11
Patent number
US03992408

Reaction notes

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