Carbon Dioxide → Octa-1,3-dien-1-ol
Reaction equation
O.[C:2](=[O:4])=O.[CH2:5]=[CH:6][CH:7]=[CH2:8].[C:9](O)(C)([CH3:11])[CH3:10]>>[CH:2]([OH:4])=[CH:5][CH:6]=[CH:7][CH2:8][CH2:10][CH2:9][CH3:11]Participants
5
Procedure
For example, when a mixture of carbon dioxide, water, butadiene, dioxane solvent and palladium catalyst is reacted under certain conditions, a 50-60 percent yield of octadienol is realized compared to the 10 percent yield of octadienol that is obtained in the absence of carbon dioxide. In t-butanol solvent, a mixture of water, carbon dioxide, butadiene, solvent and catalyst yields at least 70 percent octadienol compared to a 10 percent yield in the absence of carbon dioxide. The total reaction is outlined below. ##SPC1##
Sources & evidence
- ORD record
- ord-c3e49b8de1ab4979a78297397058b255
- Source dataset
- uspto-grants-1976_11
- Patent number
- US03992456
Reaction notes
Loading…