Hydrazine → HCID 178513179, compound

HRID 1730479Notes

Reaction equation

HRID 1730479 reaction equation
[ClH:1].Cl[C:3]1[CH:15]=[CH:14][C:6]([CH:7]=[N:8][NH:9][C:10](=[NH:13])SC)=[CH:5][CH:4]=1.[NH2:16][NH2:17]>C(O)C>[NH2:16][NH:17][C:10]([NH:9][NH:8][CH2:7][C:6]1[CH:14]=[CH:15][C:3]([Cl:1])=[CH:4][CH:5]=1)=[NH:13]

Participants

4

Reactant 2

HCID 9321HydrazineHCID 178504058HCID 178504058, compound

Product 1

HCID 178513179HCID 178513179, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

The same compound is synthesized by the reaction of equimolar quantities ofp-chlorobenzylhydrazine and methyl-3-(4-chlorobenzylidene)thiocarbazimidatehydrochloride (see Example 10) in hot ethanol. It is also prepared by the reaction of equimolar amounts of 1-(p-chlorobenzyl)-S-methylisothiosemicarbazide and hydrazine in warm ethanol, which affords 1-amino-3-(p-chlorobenzylamino)guanidine, followed by treatment of the latter with an equimolar quantity of p-chlorobenzaldehyde in hot isopropanol.

Sources & evidence

ORD record
ord-38468505759c4437af74da3fe5444d5c
Source dataset
uspto-grants-1976_11
Patent number
US03992446

Reaction notes

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