HCID 21498287, compound → HCID 21498281, compound

HRID 1730510Notes

Reaction equation

HRID 1730510 reaction equation
[C:1]([O:4][CH2:5][C:6]1[C:10]2[CH2:11][N:12]([CH2:16][C:17]3[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=3)[CH2:13][CH:14]([CH3:15])[C:9]=2[N:8]([CH2:23][C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[C:7]=1[C:30]1[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=1)(=O)C>CO>[CH2:23]([N:8]1[C:9]2[CH:14]([CH3:15])[CH2:13][N:12]([CH2:16][C:17]3[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=3)[CH2:11][C:10]=2[C:6]([CH2:5][O:4][CH3:1])=[C:7]1[C:30]1[CH:31]=[CH:32][CH:33]=[CH:34][CH:35]=1)[C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1

Participants

3

Reactant 1

HCID 21498287HCID 21498287, compound

Product 1

HCID 21498281HCID 21498281, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

3-Acetoxymethyl-1,5-dibenzyl-4,5,6,7-tetrahydro-7-methyl-2-phenyl-1H-pyrrolo[3,2-c]pyridine (200 mg), prepared according to Example 16, was dissolved in methanol (10 ml) by briefly warming. On cooling, the title compound wasobtained as white needles, 125 mg. M.pt. 140°-1° C (Found: C,82.5; H, 7.5; N, 6.4. C30H32N2O requires: C, 82.5; H, 7.4; N, 6.4%).

Workup

  1. temperatureby briefly warming
  2. temperatureOn cooling

Sources & evidence

ORD record
ord-220549ca9d034639b5ffcc31c6db3bb2
Source dataset
uspto-grants-1976_11
Patent number
US03992544

Reaction notes

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