HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetonitrile → (4-Carboxybutyl)triphenylphosphonium bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetonitrile | HCID 6342 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 5-Bromovaleric acid | HCID 16368 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | (4-Carboxybutyl)triphenylphosphonium bromide | HCID 161236 | — |
Reaction Steps
A mixture of 103 g. of 5-bromoval eric acid and 152 g. of triphenylphosphine in 400 ml. of acetonitrile is refluxed for 48 hours, cooled, diluted with 100 ml. of benzene and allowed to crystallize. The crystals are filtered, washed with benzene and ether, to yield colorless material, m.p. 207°-209° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03993674 |
| Source dataset | uspto-grants-1976_11 |
| ORD ID | ord-5095a63194d0460292d3e56f92bca580 |
| Source note | uspto-grants-1976_11 |