Epichlorohydrin → HCID 54125222, compound

Participants

Reaction Conditions

Reaction Steps

A mixture of 146.1 g of 3-(diethoxyphosphonoethyl)-5,5-dimethyl-hydantoin (0.5 mol), 694 g of epichlorohydrin (7.5 mols) and 0.5 g of tetramethylammonium chloride is stirred for 105 minutes at 105° C. 44 g of 50% strength aqueous sodium hydroxide solution are added dropwise over the course of 3 hours at 60° C, analogously to Example 1 (c). The mixture is worked up analogously to Example 1 (c) and 157 g of a yellow, clear resin (90.2% of theory) with 2.74 epoxide equivalents/kg (95.5% of theory) and a phosphorus content of 6.13% are obtained.

Provenance & Evidence