2-Hydroxy-2,5-dimethylhex-4-en-3-one → 2-Methyl-2-hepten-4-one

HRID 1731020Notes

Reaction equation

HRID 1731020 reaction equation
[CH3:1][C:2](=[CH:4][C:5](=[O:10])[C:6]([CH3:9])(O)C)[CH3:3].[CH:11](C=C1CC[C@H]2[C@H]3[C@H](CC[C@]12C)[C@]1(C)C(C[C@@H](O)CC1)=CC3)=O.C(C=C1CC[C@H]2[C@H]3[C@H](CC[C@]12C)C1CCC(=O)CC=1CC3)=O.CCC1C[C@@H]2[C@H](CC[C@@H]3[C@@H]4C(=CC(=O)CC4)CC[C@H]32)C1=CC=O>>[CH3:3][C:2](=[CH:4][C:5](=[O:10])[CH2:6][CH2:9][CH3:11])[CH3:1]

Participants

5

Reactant 4

HCID 137622312-Hydroxy-2,5-dimethylhex-4-en-3-oneHCID 86734220HCID 86734220, compoundHCID 86734221HCID 86734221, compoundHCID 86734222HCID 86734222, compound

Product 1

HCID 311382-Methyl-2-hepten-4-one

Procedure

2,5-dimethyl-hex-2-en-5-ol-4-one; 17-(formylmethylene)-androst-5-en-3 β -ol; 17-(formylmethylene)-estr-5(10)-en-3-one; 13 β-ethyl-17-(formylmethylene)-gon-4-en-3-one; and

Sources & evidence

ORD record
ord-8889c4acb939460298c041354db2201d
Source dataset
uspto-grants-1976_11
Patent number
US03994936

Reaction notes

Loading…