HRID1731021

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7966

Cyclohexanol

C6H12O

结构：O[Si](c1ccc(Br)cc1)(c1ccc(Br)cc1)c1ccc(Br)cc1

HCID21494694

Tris(4-bromophenyl)silanol

C18H13Br3OSi

结构：C[Si](C)(C)O[V+2](O[Si](C)(C)C)O[Si](C)(C)C.[O-2]

HCID178504322

未命名化合物

PRODUCTS

生成物

结构：Brc1ccc([Si](O[V+2](OC2CCCCC2)O[Si](c2ccc(Br)cc2)(c2ccc(Br)cc2)c2ccc(Br)cc2)(c2ccc(Br)cc2)c2ccc(Br)cc2)cc1.[O-2]

HCID178419406

未命名化合物

PROCEDURE

实验过程

tris-(trimethyl siloxy)-vanadium oxide is reacted with tri-(p-bromophenyl)-silanol and cyclohexanol in a mol ratio of 1:2:1 parts by volume to produce bis-[tri-(p-bromophenyl)-siloxy]-cyclohexyloxy-vanadium oxide [mol peak = 1184 ref. to79Br]; and

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-bc8b79f108ee432db45ecbaa5c7c1139
来源数据集: uspto-grants-1976_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US03994936
来源说明: uspto-grants-1976_11

反应 SMILES

[O-2].[CH3:2][Si:3]([CH3:17])([CH3:16])[O:4][V+2:5](O[Si](C)(C)C)[O:6][Si](C)(C)C.[Br:18][C:19]1[CH:24]=[CH:23][C:22]([Si:25]([C:34]2[CH:39]=[CH:38][C:37]([Br:40])=[CH:36][CH:35]=2)([C:27]2[CH:32]=[CH:31][C:30]([Br:33])=[CH:29][CH:28]=2)[OH:26])=[CH:21][CH:20]=1.[CH:41]1(O)[CH2:46][CH2:45][CH2:44][CH2:43][CH2:42]1>>[O-2:4].[Br:33][C:30]1[CH:31]=[CH:32][C:27]([Si:25]([C:34]2[CH:39]=[CH:38][C:37]([Br:40])=[CH:36][CH:35]=2)([C:22]2[CH:23]=[CH:24][C:19]([Br:18])=[CH:20][CH:21]=2)[O:26][V+2:5]([O:4][Si:3]([C:17]2[CH:21]=[CH:20][C:19]([Br:18])=[CH:24][CH:23]=2)([C:16]2[CH:32]=[CH:31][C:30]([Br:33])=[CH:29][CH:28]=2)[C:2]2[CH:35]=[CH:36][C:37]([Br:40])=[CH:38][CH:39]=2)[O:6][CH:41]2[CH2:46][CH2:45][CH2:44][CH2:43][CH2:42]2)=[CH:28][CH:29]=1