Cyclohexanol → HCID 178419406, compound

HRID 1731021Notes

Reaction equation

HRID 1731021 reaction equation
[O-2].[CH3:2][Si:3]([CH3:17])([CH3:16])[O:4][V+2:5](O[Si](C)(C)C)[O:6][Si](C)(C)C.[Br:18][C:19]1[CH:24]=[CH:23][C:22]([Si:25]([C:34]2[CH:39]=[CH:38][C:37]([Br:40])=[CH:36][CH:35]=2)([C:27]2[CH:32]=[CH:31][C:30]([Br:33])=[CH:29][CH:28]=2)[OH:26])=[CH:21][CH:20]=1.[CH:41]1(O)[CH2:46][CH2:45][CH2:44][CH2:43][CH2:42]1>>[O-2:4].[Br:33][C:30]1[CH:31]=[CH:32][C:27]([Si:25]([C:34]2[CH:39]=[CH:38][C:37]([Br:40])=[CH:36][CH:35]=2)([C:22]2[CH:23]=[CH:24][C:19]([Br:18])=[CH:20][CH:21]=2)[O:26][V+2:5]([O:4][Si:3]([C:17]2[CH:21]=[CH:20][C:19]([Br:18])=[CH:24][CH:23]=2)([C:16]2[CH:32]=[CH:31][C:30]([Br:33])=[CH:29][CH:28]=2)[C:2]2[CH:35]=[CH:36][C:37]([Br:40])=[CH:38][CH:39]=2)[O:6][CH:41]2[CH2:46][CH2:45][CH2:44][CH2:43][CH2:42]2)=[CH:28][CH:29]=1

Participants

4

Reactant 3

HCID 7966CyclohexanolHCID 21494694Tris(4-bromophenyl)silanolHCID 178504322HCID 178504322, compound

Product 1

HCID 178419406HCID 178419406, compound

Procedure

tris-(trimethyl siloxy)-vanadium oxide is reacted with tri-(p-bromophenyl)-silanol and cyclohexanol in a mol ratio of 1:2:1 parts by volume to produce bis-[tri-(p-bromophenyl)-siloxy]-cyclohexyloxy-vanadium oxide [mol peak = 1184 ref. to79Br]; and

Sources & evidence

ORD record
ord-bc8b79f108ee432db45ecbaa5c7c1139
Source dataset
uspto-grants-1976_11
Patent number
US03994936

Reaction notes

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