HRID1731023

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID24410

未命名化合物

结构：O[Si](c1ccc(Br)cc1)(c1ccc(Br)cc1)c1ccc(Br)cc1

HCID21494694

Tris(4-bromophenyl)silanol

C18H13Br3OSi

PRODUCTS

生成物

结构：Brc1ccc([Si](O[V+2](O[Si](c2ccc(Br)cc2)(c2ccc(Br)cc2)c2ccc(Br)cc2)O[Si](c2ccc(Br)cc2)(c2ccc(Br)cc2)c2ccc(Br)cc2)(c2ccc(Br)cc2)c2ccc(Br)cc2)cc1.[O-2]

HCID178419407

未命名化合物

PROCEDURE

实验过程

vanadium oxytrichloride is reacted with tri-(p-bromophenyl)-silanol [m.p.: 120°- 121° C.] to produce tris-[tri-(p-bromophenyl)-siloxy]-vanadium oxide [m.p.: 175° C];

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-701f37e90eb74016b4447dda848c1246
来源数据集: uspto-grants-1976_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US03994936
来源说明: uspto-grants-1976_11

反应 SMILES

[O:1]=[V:2].Cl.Cl.Cl.[Br:6][C:7]1[CH:12]=[CH:11][C:10]([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)([C:15]2[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=2)[OH:14])=[CH:9][CH:8]=1>>[O-2:14].[Br:21][C:18]1[CH:19]=[CH:20][C:15]([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)([C:10]2[CH:11]=[CH:12][C:7]([Br:6])=[CH:8][CH:9]=2)[O:14][V+2:2]([O:14][Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)([C:10]2[CH:11]=[CH:12][C:7]([Br:6])=[CH:8][CH:9]=2)[C:15]2[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=2)[O:1][Si:13]([C:15]2[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=2)([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)[C:10]2[CH:11]=[CH:12][C:7]([Br:6])=[CH:8][CH:9]=2)=[CH:16][CH:17]=1