Vanadium trichloride oxide → HCID 178419407, compound

HRID 1731023Notes

Reaction equation

HRID 1731023 reaction equation
[O:1]=[V:2].Cl.Cl.Cl.[Br:6][C:7]1[CH:12]=[CH:11][C:10]([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)([C:15]2[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=2)[OH:14])=[CH:9][CH:8]=1>>[O-2:14].[Br:21][C:18]1[CH:19]=[CH:20][C:15]([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)([C:10]2[CH:11]=[CH:12][C:7]([Br:6])=[CH:8][CH:9]=2)[O:14][V+2:2]([O:14][Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)([C:10]2[CH:11]=[CH:12][C:7]([Br:6])=[CH:8][CH:9]=2)[C:15]2[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=2)[O:1][Si:13]([C:15]2[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=2)([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)[C:10]2[CH:11]=[CH:12][C:7]([Br:6])=[CH:8][CH:9]=2)=[CH:16][CH:17]=1

Participants

3

Reactant 2

HCID 24410Vanadium trichloride oxideHCID 21494694Tris(4-bromophenyl)silanol

Product 1

HCID 178419407HCID 178419407, compound

Procedure

vanadium oxytrichloride is reacted with tri-(p-bromophenyl)-silanol [m.p.: 120°- 121° C.] to produce tris-[tri-(p-bromophenyl)-siloxy]-vanadium oxide [m.p.: 175° C];

Sources & evidence

ORD record
ord-701f37e90eb74016b4447dda848c1246
Source dataset
uspto-grants-1976_11
Patent number
US03994936

Reaction notes

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