Sodium Hydroxide → HCID 547246, compound

HRID 1731203Notes

Reaction equation

HRID 1731203 reaction equation
C(O)(=O)/C=C\C(O)=O.[CH3:9][N:10]([CH3:29])[CH2:11][CH2:12][CH:13]1[C:19]2[CH:20]=[CH:21][CH:22]=[CH:23][C:18]=2[C:17](=[CH2:24])[C:16]2[CH:25]=[CH:26][CH:27]=[CH:28][C:15]=2[CH2:14]1.[OH-].[Na+]>C(Cl)Cl>[CH3:29][N:10]([CH3:9])[CH2:11][CH2:12][CH:13]1[C:19]2[CH:20]=[CH:21][CH:22]=[CH:23][C:18]=2[C:17](=[CH2:24])[C:16]2[CH:25]=[CH:26][CH:27]=[CH:28][C:15]=2[CH2:14]1

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 20055587HCID 20055587, compound

Product 1

HCID 547246HCID 547246, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

To a mixture of 5 g. of 10-(2-dimethylaminoethyl)-10,11-dihydro-5-methylene-5H-dibenzo[a,d]cycloheptene maleate in 150 ml. of methylene chloride there is added 50 ml. of 2N-sodium hydroxide, the mixture is shaken, the methylene chloride is dried, filtered and evaporated in vacuo to give 10-(2-dimethylaminoethyl)-10,11-dihydro-5-methylene-5H-dibenzo[a,d]cycloheptene.

Workup

  1. additionTo a mixture of 5 g
  2. dry with materialthe methylene chloride is dried
  3. filtrationfiltered
  4. customevaporated in vacuo

Sources & evidence

ORD record
ord-af4a21aa3369449f921ed1c7d876dd59
Source dataset
uspto-grants-1976_11
Patent number
US03994961

Reaction notes

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