Bromine → HCID 20228873, compound

HRID 1731392Notes

Reaction equation

HRID 1731392 reaction equation
[Br:1]Br.[F:3][C-:4]1[C:8]([F:10])([F:9])[C:7]([F:12])([F:11])[C:6]([F:14])([F:13])[C:5]1([F:16])[F:15].CN([S+](N(C)C)N(C)C)C>C(#N)C1C=CC=CC=1>[Br:1][C:4]1([F:3])[C:5]([F:15])([F:16])[C:6]([F:13])([F:14])[C:7]([F:11])([F:12])[C:8]1([F:10])[F:9]

Participants

4

Reactant 2

HCID 24408BromineHCID 20228872HCID 20228872, compound

Product 1

HCID 20228873HCID 20228873, compound

Reagents, catalysts & solvents 1

HCID 7505BenzonitrileSolvent

Procedure

Bromine was added to a solution of tris(dimethylamino)sulfonium 1,2,2,3,3,4,4,5,5-nonafluorocyclopentanide in benzonitrile, prepared as described in Example 5. Distillation of the reaction mixture gave bromononafluorocyclopentane as a colorless liquid: b.p. 64°-65°; 19F NMR (CCl3F) δ -112.4 ppm (d, J=262 Hz, 2F), -136.2 ppm (d, J=262 Hz, 2F), -141.4 ppm (m, 1F), -125.4 ppm (d, J=255 Hz, 2F) and -127.8 ppm (d, J=255 Hz, 2F).

Workup

  1. customprepared
  2. distillationDistillation of the reaction mixture

Sources & evidence

ORD record
ord-c737f4acd57e4ff4802816137a0d3922
Source dataset
uspto-grants-1986_11
Patent number
US04621126

Reaction notes

Loading…