Acetaldehyde → HCID 53950079, compound

HRID 1731428Notes

Reaction equation

Br[C:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([CH:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1.[CH:16](=[O:18])[CH3:17]>>[OH:18][CH2:16][CH2:17][C:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([CH:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 177Acetaldehyde

HCID 125298271-Bromoanthracene

Product 1

HCID 53950079HCID 53950079, compound

Procedure

For instance, a Grignard reagent prepared from bromonaphthalene is reacted with acetophenone to obtain 1-phenyl-1-naphthylethanol which is then dehydrated to obtain 1-phenyl-1-naphthylethylene. Further, a Grignard reagent prepared from bromoanthracene is reacted with acetaldehyde to obtain hydroxyethylanthracene which is then dehydrated to obtain vinylanthracene.

Sources & evidence

ORD record: ord-77600305ba894417939595413ff0160d
Source dataset: uspto-grants-1986_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04621302

Reaction notes

Loading…