HCID 13746716, compound → HCID 20228223, compound

HRID 1731640Notes

Reaction equation

HRID 1731640 reaction equation
[O:1]=[C:2]1[C:23]2[C:9]3[CH2:10][CH2:11][C:12]4[CH:18]=[CH:17][C:16]([C:19]([O:21]C)=[O:20])=[CH:15][C:13]=4[S:14][C:8]=3[CH:7]=[CH:6][C:5]=2[CH2:4][CH2:3]1.[O:24]=C1C2C3SC4=CCCC=C4C=C(C(OC)=O)C=3C=CC=2CC1>>[O:24]=[S:14]1[C:8]2[CH:7]=[CH:6][C:5]3[CH2:4][CH2:3][C:2](=[O:1])[C:23]=3[C:9]=2[CH2:10][CH2:11][C:12]2[CH:18]=[CH:17][C:16]([C:19]([OH:21])=[O:20])=[CH:15][C:13]1=2

Participants

3

Reactant 2

HCID 13746716HCID 13746716, compoundHCID 20228201HCID 20228201, compound

Product 1

HCID 20228223HCID 20228223, compound

Procedure

Substituting an equivalent amount of methyl 1-oxo-2,3,11,12-tetrahydro-1H-benzo[b]indeno[4,5-f]-thiepin-8-carboxylate in Example 38, Step A, in place of methyl 1-oxo-2,3,9,10-tetrahydro-1H-benzo[b]-indeno[5,4-f]thiepin-6-carboxylate and taking the product through Step B of this example provided the title compound.

Sources & evidence

ORD record
ord-2ec23b9f7d4043328c617762e329f815
Source dataset
uspto-grants-1986_11
Patent number
US04622403

Reaction notes

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