Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Pyridine | HCID 1049 | — |
| Reactant | Silver Nitrate | HCID 24470 | — |
| Reactant | HCID 13456947 | HCID 13456947 | — |
| Solvent | Methanol | HCID 887 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 178419108 | HCID 178419108 | 109.8% |
Reaction Steps
To a solution of 3-[(Z)-2-(tritylthio)vinyl]pyridine (690 mg) in a mixture of tetrahydrofuran (3 ml), methanol (5 ml) and pyridine (0.147 ml) was dropwise added a solution of silver nitrate (371 mg) in methanol (20 ml) at ambient temperature. The reaction mixture was stirred at 40° C. in dark. The precipitate was collected, washed with methanol and dried over phosphorus pentoxide to give [(Z)-2-(3-pyridyl)vinylthio]silver (487 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04622318 |
|---|
| Source dataset | uspto-grants-1986_11 |
|---|
| ORD ID | ord-73cc1c65d2074a5a8a61f53ef3225c44 |
|---|
| Source note | uspto-grants-1986_11 |
|---|
