2-Methoxybenzoyl chloride → HCID 6736106, compound

Participants

Reaction Steps

A solution of 2-methoxybenzoyl chloride (3.41 g, 0.020 mole) in 50 ml of toluene was added dropwise to a stirred solution of 1,2-diethyl-4-aminopyrazolidine (2.86 g. 0.020 mole) in 100 ml of toluene. The mixture was stirred at ambient temperature for 2 hrs, and then at reflux temperature for 2 hrs. After standing for 16 hrs, the mixture was extracted with 100 ml of 10% sodium bicarbonate solution. The toluene layer was dried over magnesium sulfate and concentrated to give 4.32 g (81.6%) of oil. The liquid was distilled over magnesium sulfate, b.p. 160° C./0.020 mm Hg, to give 2.52 g of a clear, yellow oil.

Provenance & Evidence