HCID 20305771, compound → HCID 54508543, compound

HRID 1732261Notes

Reaction equation

HRID 1732261 reaction equation
O(CC(C)CCCC(C)=CC[Br:27])[Si](C(C)(C)C)(C1C=CC=CC=1)C1C=CC=CC=1.[CH2:30]([O:37][CH2:38][CH:39]([CH3:48])[CH2:40][CH2:41][CH2:42][C:43]([CH3:47])(O)[CH:44]=[CH2:45])[C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1>>[CH2:30]([O:37][CH2:38][CH:39]([CH3:48])[CH2:40][CH2:41][CH2:42][C:43]([CH3:47])=[CH:44][CH2:45][Br:27])[C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1

Participants

3

Reactant 2

HCID 20305771HCID 20305771, compoundHCID 53760007HCID 53760007, compound

Product 1

HCID 54508543HCID 54508543, compoundYield 90%

Procedure

Following the procedure for the synthesis of 8-t-butyldiphenylsiloxy-1-bromo-3,7-dimethyl-oct-2-ene, treatment of 8-benzyloxy-3,7-dimethyl-1-octen-3-ol (0.605 g) gives 8-benzyloxy-1-bromo-3,7-dimethyl-oct-2-ene (0.675 mg, 90% yield, 7:3 E:Z).

Sources & evidence

ORD record
ord-31683d73c85c4eeda3b644a04a2d27e6
Source dataset
uspto-grants-1980_12
Patent number
US04237055

Reaction notes

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