HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → HCID 20306038, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 4-Hydroxybenzamide | HCID 65052 | — |
| Reactant | ethyl N-ethoxycarbonyliminocarbamate | HCID 220568 | — |
| Reactant | HCID 14022405 | HCID 14022405 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 20306038 | HCID 20306038 | 44% |
Reaction Steps
N-Acetyl-4-(2-hydroxyethoxy)piperidine (1.0 g.), 4-hydroxybenzamide (0.82 g.), diethyl azodicarboxylate (1.12 g.) and triphenylphosphine (1.68 g.) in tetrahydrofuran (30 ml.) were stirred at room temperature for 66 hours. The precipitated solid was collected and dried to give 4-[2-(N-acetyl-4-piperidyloxy)ethoxy]benzamide (0.72 g.), m.p. 154°-155° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04237138 |
| Source dataset | uspto-grants-1980_12 |
| ORD ID | ord-a17fef1402c44cc6ae6ebae89c2f7c9f |
| Source note | uspto-grants-1980_12 |