3-Hydroxymethyl-10,11-dihydrodibenzo[b,f]thiepin → 3-Hydroxymethyl-8-nitro-dibenzo[b,f]thiepin-5-oxide

HRID 1732357Notes

Reaction equation

HRID 1732357 reaction equation
[OH:1][CH2:2][C:3]1[CH:4]=[CH:5][C:6]2[CH:12]=[CH:11][C:10]3[CH:13]=[C:14]([N+:17]([O-:19])=[O:18])[CH:15]=[CH:16][C:9]=3[S:8][C:7]=2[CH:20]=1.[OH:21]CC1C=CC2CCC3C=CC=CC=3SC=2C=1>>[OH:1][CH2:2][C:3]1[CH:4]=[CH:5][C:6]2[CH:12]=[CH:11][C:10]3[CH:13]=[C:14]([N+:17]([O-:19])=[O:18])[CH:15]=[CH:16][C:9]=3[S:8](=[O:21])[C:7]=2[CH:20]=1

Participants

3

Reactant 2

HCID 202555023-Hydroxymethyl-10,11-dihydrodibenzo[b,f]thiepinHCID 203061553-Hydroxymethyl-8-nitro-dibenzo[b,f]thiepin

Product 1

HCID 203061603-Hydroxymethyl-8-nitro-dibenzo[b,f]thiepin-5-oxide

Procedure

Repeat the process of Example 2, substituting an equivalent quantity of 3-hydroxymethyl-8-nitro-dibenzo[b,f]thiepin for the 3-hydroxymethyl-10,11-dihydrodibenzo[b,f]thiepin, to obtain the title product.

Sources & evidence

ORD record
ord-becea5016ece46b5a4ef04efa04fd69c
Source dataset
uspto-grants-1980_12
Patent number
US04237160

Reaction notes

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