Sodium Cyanide → HCID 23716990, compound

HRID 1732562Notes

Reaction equation

HRID 1732562 reaction equation
[C:1]([CH:3]1[CH2:9][CH2:8][S:5](=[O:7])(=[O:6])[CH2:4]1)#[N:2].[C-:10]#[N:11].[Na+:12]>>[C:1]([CH:3]([CH2:4][C:10]#[N:11])[CH2:9][CH2:8][S:5]([O-:7])=[O:6])#[N:2].[Na+:12]

Participants

3

Reactant 2

HCID 8929Sodium CyanideHCID 164495681,1-dioxo-1-thiolane-3-carbonitrile

Product 1

HCID 23716990HCID 23716990, compound

Procedure

The following runs demonstrate the reaction of 3-cyanosulfolane with sodium cyanide to give sodium 3,4-dicyanobutane-1-sulfinate which was then either oxidized to sodium 3,4-dicyanobutane-1-sulfonate or converted by reaction with methyl iodide to the corresponding methylsulfone, i.e., 2-(2-methylsulfonylethyl)succinonitrile.

Sources & evidence

ORD record
ord-52bc2f144da6419bb9630b67f0ad37ee
Source dataset
uspto-grants-1980_12
Patent number
US04238408

Reaction notes

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