HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,2-Diethoxyethylamine → N-(2,2-Diethoxyethyl)-1-(methylsulfanyl)-2-nitroethen-1-amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,2-Diethoxyethylamine | HCID 69524 | — |
| Reactant | 1-Nitro2-methylthio-2-methylsulphinylethylene | HCID 54487094 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | N-(2,2-Diethoxyethyl)-1-(methylsulfanyl)-2-nitroethen-1-amine | HCID 71398340 | 49% |
Reaction Steps
A solution of aminoacetaldehyde diethylacetal (11g, 0.08 mol) and 1-nitro-2-methylthio-2-methylsulphinyl-ethylene (15g, 0.08 mol) in methanol (200 ml) was stirred for 21/2 hours at room temperature. The solvent was removed in vacuo leaving a yellow oily residue which after trituration with propan-2-ol gave 1-nitro-2-methylthio-2-(2,2-diethoxy-ethylamino)ethylene (9.8, 49%) m.p. 72-74°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04238494 |
| Source dataset | uspto-grants-1980_12 |
| ORD ID | ord-54d4c138c89046aa90702c41bbb48096 |
| Source note | uspto-grants-1980_12 |