Phenyl isocyanate → HCID 20304012, compound

Participants

Reaction Conditions

Reaction Steps

2-Phenylthiomethyl-2-imidazoline (4.8 g; 0.025 mole) was dissolved in CH2Cl2 (200 ml) and the solution cooled to -15° C. before treating dropwise with fresh phenyl isocyanate (3.0 g; 0.025 moles) over 15 minutes. The mixture was allowed to warm to room temperature and stirring continued for a further 2 hours. The solvent was then evaporated in vacuo and the residue recrystallised from ethyl acetate, to give a solid, m.p. 117.4° to 119.0° C.

Provenance & Evidence