Hydrogen Peroxide → HCID 20301446, compound

Participants

Reaction Steps

To a solution of 300 g of 1,1,3-trimethyl-3-(5-butylthio-1,3,4-thiadiazol-2-yl) urea in 1.9 ltr glacial acetic acid there are added in drops at room temperature and with agitation 136 g of perhydrol. The temperature then rises to 28° C. After standing for 5 days, the perhydrol excess is destroyed with manganese dioxide, the glacial acetic acid is vacuum-distilled to a very large extent, and the residue taken up in methylene chloride, is treated twice with active carbon, the solvent distilled, and the remaining oil dried in high vacuum.

Provenance & Evidence