Sulfuryl chloride → HCID 12593653, compound

HRID 1732935Notes

Reaction equation

HRID 1732935 reaction equation
S(Cl)(Cl)(=O)=O.[C:6]1([S:12][CH:13]2[C:17]([C:18]#[N:19])=[CH:16][S:15][CH2:14]2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1>C(Cl)Cl>[C:6]1([S:12][C:13]2[C:17]([C:18]#[N:19])=[CH:16][S:15][CH:14]=2)[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 20300155HCID 20300155, compound

Product 1

HCID 12593653HCID 12593653, compoundYield 90%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

3.6 Parts by volume of sulfuryl chloride in 25 parts by volume of methylene chloride are added, at 0° C., to a solution of 8.76 parts of 3-phenylthio-4-dihydrothiophene-nitrile in 100 parts by volume of methylene chloride. During the reaction, nitrogen is passed into the mixture. The end product is isolated from the reaction mixture by the method described in Example 5c. 7.8 parts (90% of theory) of 3-phenylthio-4-thiophene-nitrile of melting point 32°-34° C. are obtained.

Workup

  1. customDuring the reaction, nitrogen
  2. customThe end product is isolated from the reaction mixture by the method

Sources & evidence

ORD record
ord-f61263d7b3aa490299fa3f40fa013498
Source dataset
uspto-grants-1980_12
Patent number
US04239897

Reaction notes

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