HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Methyl-4,6-androstadiene-3,17,19-trione → 4,7alpha-Dimethyl-4-androstene-3beta,17beta,9-triol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Methyl-4,6-androstadiene-3,17,19-trione | HCID 53720057 | — |
| Reactant | 4,6-Androstadiene-3,17,19-trione | HCID 53751173 | — |
| Reactant | 17beta-Hydroxy-17alpha-methyl-4,6-androstadiene-3,19-dione | HCID 86735693 | — |
| Reactant | 17beta-Hydroxy-17alpha-propinyl-4,6-androstadiene-3,19-dione | HCID 131711096 | — |
| Product | 4,7alpha-Dimethyl-4-androstene-3beta,17beta,9-triol | HCID 70585417 | — |
Reaction Steps
Substituting 4-methyl-4,6-androstadiene-3,17,19-trione, 17β-hydroxy-17α-methyl-4,6-androstadiene-3,19-dione and 17β-hydroxy-17α-propinyl-4,6-androstadiene-3,19-dione for the 4,6-androstadiene-3,17,19-trione above results in the formation of 4,7α-dimethyl-4-androstene-3β,17β,9-triol, 7α,17α-dimethyl-4-androstene-3β,17β,19-triol and 7α-methyl-17α-propinyl-4-androstene-3β,17β,19-triol, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04239681 |
| Source dataset | uspto-grants-1980_12 |
| ORD ID | ord-9012d0ef73d6434c9f86dd26d0ff99ad |
| Source note | uspto-grants-1980_12 |