HuagongsheHuagongshe Chemistry Print Report · For research reference only
Quinoline → 4-Methylbenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Quinoline | HCID 7047 | — |
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Reactant | Sulfur | HCID 5362487 | — |
| Reactant | HCID 86737396 | HCID 86737396 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | 4-Methylbenzaldehyde | HCID 7725 | 88% |
Reaction Steps
To a solution containing 20.8 g (0.10 moles) of p-toluylethyl-carbonate in 300 ml of tetrahydrofuran there are added 10.4 g of Pd on BaSO4 10% and 0.1 cc of a solution of sulfur and quinoline 1:3000. Proceeding as in Example I, step (6), 10.5 g of p-methylbenzaldehyde (yield 88%) are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04240984 |
| Source dataset | uspto-grants-1980_12 |
| ORD ID | ord-d19e8a266681448198d8f46c9b5a96ba |
| Source note | uspto-grants-1980_12 |