Benzoyl Peroxide → HCID 19979715, compound

HRID 1733408Notes

Reaction equation

HRID 1733408 reaction equation
[Br:1]N1C(=O)CCC1=O.[Br:9][C:10]1[CH:15]=[CH:14][C:13]([O:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)=[CH:12][C:11]=1[CH3:23].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[O:16]([C:13]1[CH:14]=[CH:15][C:10]([Br:9])=[C:11]([CH2:23][Br:1])[CH:12]=1)[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 128585521-Bromo-2-methyl-4-phenoxybenzene

Product 1

HCID 19979715HCID 19979715, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

N-Bromosuccinimide (16.2 g) was added to a solution of 2-bromo-5-phenoxytoluene (15.3 g) in carbon tetrachloride (50 mls) containing benzoyl peroxide (0.05 g) and the mixture refluxed for ten hours. The precipitate of succinimide was filtered off and the filtrate washed with N-sodium hydroxide solution followed by water. Drying over magnesium sulphate and evaporation of the solvent gave, as a light yellow oil, 4-phenoxy-2-bromomethylphenyl bromide.

Workup

  1. temperaturethe mixture refluxed for ten hours
  2. filtrationThe precipitate of succinimide was filtered off
  3. washthe filtrate washed with N-sodium hydroxide solution
  4. dry with materialDrying over magnesium sulphate and evaporation of the solvent

Sources & evidence

ORD record
ord-1de0b030e97c4eb2baca5b8491fe176c
Source dataset
uspto-grants-1980_12
Patent number
US04242121

Reaction notes

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