Sulfuryl chloride → HCID 12231065, compound

HRID 1733603Notes

Reaction equation

HRID 1733603 reaction equation
[CH3:1][O:2][CH:3]1[CH:7]=[CH:6][S:5][CH:4]1[C:8]#[N:9].S(Cl)(Cl)(=O)=O>C(Cl)(Cl)Cl>[CH3:1][O:2][C:3]1[CH:7]=[CH:6][S:5][C:4]=1[C:8]#[N:9]

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 20300182HCID 20300182, compound

Product 1

HCID 12231065HCID 12231065, compoundYield 91%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

14.1 parts of 3-methoxy-2-cyanodihydrothiophene in 80 parts by volume of chloroform are reacted with 6.75 parts of sulfuryl chloride in 20 parts by volume of chloroform for 0.5 hour at 0° C. The end product is isolated from the reaction mixture by the method described in Example 14(c). 12.6 parts (91% of theory) of 3-methoxy-2-cyanothiophene of boiling point 73° C./0.16 mbar are obtained.

Workup

  1. customThe end product is isolated from the reaction mixture by the method

Sources & evidence

ORD record
ord-c1e0f893799a44a0aa0bb35ad9a3d029
Source dataset
uspto-grants-1980_12
Patent number
US04242518

Reaction notes

Loading…