HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)- → alpha-Cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(-2-(isopropoxyimino)propyl)cyclopropanecarboxylat
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)- | HCID 11083 | — |
| Reactant | Benzenemethanol, 2,6-dichloro- | HCID 27156 | — |
| Reactant | N-(Hydroxymethyl)-3,4,5,6-tetrahydrophthalimide | HCID 78597 | — |
| Reactant | 3-Phenoxy-alpha-ethynylbenzylalcohol | HCID 12919092 | — |
| Reactant | alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(neopentoxyimino)propyl)cyclopropanecarboxylate | HCID 53762777 | — |
| Reactant | 3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(isobutoxyimino)propyl)cyclopropanecarboxylate | HCID 54499472 | — |
| Reactant | alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclopropylmethoxyimino)propyl)cyclopropanecarboxylate | HCID 86737170 | — |
| Reactant | alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclobutylmethoxyimino)propyl)cyclopropanecarboxylate | HCID 86737171 | — |
| Product | alpha-Cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(-2-(isopropoxyimino)propyl)cyclopropanecarboxylat | HCID 53742917 | — |
Reaction Steps
Following procedures similar to Embodiment II above: α-cyano -3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(neopentoxyimino)propyl)cyclopropanecarboxylate, 3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(isobutoxyimino)propyl)cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclopropylmethoxyimino)propyl)cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclobutylmethoxyimino)propyl)cyclopropanecarboxylate are prepared as well as the corresponding esters in the racemic and (1R,trans) form and similar esters with other alcohols: α-ethynyl-3-phenoxybenzyl alcohol, 3,4,5,6-tetrahydrophthalimidomethyl alcohol, 2,6-dichlorobenzyl alcohol, 2-chloro-4-phenyl-2-butenl-o1 and allethrolone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04242521 |
| Source dataset | uspto-grants-1980_12 |
| ORD ID | ord-ee2702e9dd3e44b1b8632b1eefac668c |
| Source note | uspto-grants-1980_12 |