tert-Butoxy bis(dimethylamino)methane → HCID 54100772, compound

HRID 1733980Notes

Reaction equation

HRID 1733980 reaction equation
[N+:1]([C:4]1[CH:23]=[CH:22][C:7]([C:8]([N:10]2[CH2:16][CH2:15][CH2:14][C:13](=[O:17])[C:12]3[N:18]=[CH:19][CH:20]=[CH:21][C:11]2=3)=[O:9])=[CH:6][CH:5]=1)([O-:3])=[O:2].C(O[CH:29](N(C)C)[N:30]([CH3:32])[CH3:31])(C)(C)C>>[CH3:29][N:30]([CH:32]=[C:14]1[CH2:15][CH2:16][N:10]([C:8](=[O:9])[C:7]2[CH:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:23][CH:22]=2)[C:11]2[CH:21]=[CH:20][CH:19]=[N:18][C:12]=2[C:13]1=[O:17])[CH3:31]

Participants

3

Reactant 2

HCID 79885tert-Butoxy bis(dimethylamino)methaneHCID 10519066HCID 10519066, compound

Product 1

HCID 54100772HCID 54100772, compound

Procedure

As described for Reference Example 221, 5,6,7,8-tetrahydro-5-(4-nitrobenzoyl)-9H-pyrido[3,2-b] azepin-9-one is reacted with tert-butoxybis(dimethylamino)methane to give the product as a solid.

Sources & evidence

ORD record
ord-6eeeae2654d74964980ebc2e8a0779dc
Source dataset
uspto-grants-1996_07
Patent number
US05532235

Reaction notes

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