HCID 19437537, compound → HCID 19437563, compound

HRID 1734394Notes

Reaction equation

HRID 1734394 reaction equation
[CH2:1]([O:11][C:12]1[CH:13]=[C:14]2[C:19](=[CH:20][CH:21]=1)[CH:18]=[C:17]([C:22]#[C:23][CH:24]([O:26][C:27](=[O:30])[CH2:28][CH3:29])[CH3:25])[CH:16]=[CH:15]2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]>C(Cl)(Cl)Cl>[CH2:1]([O:11][C:12]1[CH:13]=[C:14]2[C:19](=[CH:20][CH:21]=1)[CH:18]=[C:17]([CH2:22][CH2:23][CH:24]([O:26][C:27](=[O:30])[CH2:28][CH3:29])[CH3:25])[CH:16]=[CH:15]2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

3

Reactant 1

HCID 19437537HCID 19437537, compound

Product 1

HCID 19437563HCID 19437563, compoundYield 98.5%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

In the same manner as above, 1.2 g (yield 98.5%) of 6-decyloxy-2-(3-propionyloxy-1-butyl)naphthalene, [α]D20 =-12.8° (c=1, chloroform), is obtained from 1.2 g (3 mmol) of optically active 6-decyloxy-2-(3-propionyloxy-1-butynyl)naphthalene.

Sources & evidence

ORD record
ord-4ae33e116629497ca844ad69ff8c31b7
Source dataset
uspto-grants-1996_07
Patent number
US05534188

Reaction notes

Loading…