Ammonia → Diallyl 2-aminobenzene-1,4-dicarboxylate

HRID 1736359Notes

Reaction equation

HRID 1736359 reaction equation
[N+:1]([C:4]1[CH:9]=[C:8]([C:10]([O:12][CH2:13][CH:14]=[CH2:15])=[O:11])[CH:7]=[CH:6][C:5]=1[C:16]([O:18][CH2:19][CH:20]=[CH2:21])=[O:17])([O-])=O.C(OC1C=C([N+]([O-])=O)C=CC=1C(OCC=C)=O)C=C.N>>[NH2:1][C:4]1[CH:9]=[C:8]([C:10]([O:12][CH2:13][CH:14]=[CH2:15])=[O:11])[CH:7]=[CH:6][C:5]=1[C:16]([O:18][CH2:19][CH:20]=[CH2:21])=[O:17]

Participants

4

Reactant 3

HCID 222AmmoniaHCID 241039Diallyl 2-nitrobenzene-1,4-dicarboxylateHCID 11666115HCID 11666115, compound

Product 1

HCID 19432553Diallyl 2-aminobenzene-1,4-dicarboxylate

Procedure

The above nitro compound was reduced by the method described in example 1, for the reduction of allyl 2-allyloxy-4-nitrobenzoate, except using an aqueous solution of ammonia in place of sodium bicarbonate in the work-up, to give diallyl 2-aminobenzene-1,4-dicarboxylate.

Sources & evidence

ORD record
ord-1bd6b853c3ed48ac8fbec647d45a4af5
Source dataset
uspto-grants-1996_07
Patent number
US05541178

Reaction notes

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